The usability of the IR,RAC and MRI indices of heavy metal distribution to assess the environmental quality of sewage sludge composts

To assess the environmental quality of compost, it is insufficient to use only total metal concentration. Therefore in this study, the stability of metals in compost and the environmental risk they pose were assessed by three indices that have been proposed for soils or sediments: the I_R, the RAC and the MRI. In mature composts, the highest bonding intensity was for Ni (0.79 < I_R < 0.93), then for Cu (0.56 < I_R < 0.65) and Pb (0.55 < I_R < 0.73), and the lowest for Zn (0.19 < I_R < 0.25). Although, both the I_R and the RAC are useful indices for evaluating the mobility of metals, they do not take into account their toxicity. Therefore, the overall classification of compost should also include the MRI, at which metal toxicity from the most available fractions is considered. Based on the MRI ranged between 10.0 and 11.6, all composts evaluated posed a low risk.     

Dimensions of Job Control in Computerized and Traditional Office Work and Its Health Effects

This study investigates whether a consistent relationship exists between computerization and job control. It also examines the role of job control as a predictor of stress symptoms typical for data entry and word processing (VDU) work. Two groups of VDU users and two comparable non-VDU-user groups took part in this study. A special questionnaire made it possible to assess global job control and four indexes of control related to specific aspects of work (control over choice of tasks and methods, control over time frame, control related to one’s skill, and control related to participation in the decision-making process). Results did not show an unequivocal relation between computerization and the latitude of control. The latitude of control depends on the task performed and the aspect of control we are considering. Regression analyses showed that global control is a good predictor of job satisfaction, some mood disturbances, and visual complaints. The other aspects of control are related in a variety of ways to stress symptoms. The role of a Type A behavior pattern in the relationship between job control and stress symptoms varies depending on which aspect of control is being considered. It was concluded that because of the high functional differences between various aspects of control, it is better to avoid using the concept of global control and, when possible, apply specific indexes of control.     

Developing a standard for psychosocial risk management: PAS 1010

The nature of work has changed dramatically due to globalisation, migration, technological advances and the emergence of the knowledge-based economy. These changes have been accompanied by the increased prevalence of new and emerging types of risk to workers’ health and safety, such as psychosocial risks. This paper reviews the key regulatory and voluntary standards on occupational health and safety of relevance to the management of psychosocial risks in the workplace that are applicable to the European Union member states. The review indicates that regulatory standards set the minimum level of protection for workers and voluntary standards may further enable organisations to go beyond their legal obligations. However, the review also highlights that the terms ‘stress’ and ‘psychosocial risks’ are not mentioned explicitly in most pieces of legislation leading to lack of clarity on the terminology used. While voluntary standards seek to address this, very few provide specific guidance on the process of psychosocial risk management to enable organisations to manage psychosocial risks successfully. On the basis of the review, the case for the development of a voluntary standard for psychosocial risk management is presented. The paper further discusses the recent development of such a standard and its implications at the European level.     

Effect of Nb doping on structural, optical and photocatalytic properties of flame-made TiO2 nanopowder

TiO₂:Nb nanopowders within a dopant concentration in the range of 0.1?C15?at.% were prepared by one-step flame spray synthesis. Effect of niobium doping on structural, optical and photocatalytic properties of titanium dioxide nanopowders was studied. Morphology and structure were investigated by means of Brunauer?CEmmett?CTeller isotherm, X-ray diffraction and transmission electron microscopy. Diffuse reflectance and the resulting band gap energy were determined by diffuse reflectance spectroscopy. Photocatalytic activity of the investigated nanopowders was revised for the photodecomposition of methylene blue (MB), methyl orange (MO) and 4-chlorophenol under UVA and VIS light irradiation. Commercial TiO₂-P25 nanopowder was used as a reference. The specific surface area of the powders was ranging from 42.9?m²/g for TiO₂:0.1?at.% Nb to 90.0?m²/g for TiO₂:15?at.% Nb. TiO₂:Nb particles were nanosized, spherically shaped and polycrystalline. Anatase was the predominant phase in all samples. The anatase-related transition was at 3.31?eV and rutile-related one at 3.14?eV. TiO₂:Nb nanopowders exhibited additional absorption in the visible range. In comparison to TiO₂-P25, improved photocatalytic activity of TiO₂:Nb was observed for the degradation of MB and MO under both UVA and VIS irradiation, where low doping level (Nb?<?1?at.%) was the most effective. Niobium doping affected structural, optical and photocatalytic properties of TiO₂. Low dopant level enhanced photocatalytic performance under UVA and VIS irradiation. Therefore, TiO₂:Nb (Nb?<?1?at.%) can be proposed as an efficient selective solar light photocatalyst.     

Simultaneous gas chromatographic determination of chlorpyrifos and its impurity sulfotep in liquid pesticide formulations

An analytical method for simultaneous determination of the active substance (chlorpyrifos) and its relevant impurity (sulfotep) in commercial pesticide formulations has been developed and validated. The proposed method entails extraction of the analytes from samples by sonication with acetone and analysis by gas chromatography-flame ionization detection (GC-FID). The proposed method was characterized by satisfactory accuracy and precision. The repeatability expressed as relative standard deviation (RSD) was lower than the acceptable values calculated from the modified Horwitz equation whereas individual recoveries were in the range of 98–102% and 80–120% for chlorpyrifos and sulfotep, respectively. The limit of quantification (LOQ) for the impurity (sulfotep) was 0.003 mg mL^?1 corresponding to the maximum permitted level according to Food and Agricultural Organization of the United Nations (FAO) specifications for the active substance (chlorpyrifos) being 3 g kg^?1 of the chlorpyrifos content found. The main advantage of the proposed method was a considerable reduction in the analysis time since both analytes were determined based on a single injection into the GC-FID. Analysis of real samples of commercial pesticide formulations confirmed fitness-for-purpose of the proposed method.     

Influence of 1,2,4,5-tetrazine derivatives on growth of bacterial consortium isolated from soil

This article presents the results of laboratory studies of the influence of tetrazine derivatives on the growth kinetic parameters of soil bacteria. 3,6-Dihydrazinotetrazine (DHTz), 3,6- bis(3,5-dimethylpyrazol-1-yl)-dihydro-1,2,4,5-tetrazine (DMPDHT) and N,N′-bis(1,2,4,5-tetrazine-6-(3,5-dimethylpirazylo))hydrazine (BDMPT) were applied. 3,6-Dihydrazinetetrazine had the largest influence on the growth of bacteria, reflected in a significant lengthening of the lag-phase and a decrease in the specific growth rate. Dehydrogenase activity was also determined in bacterial cultures exposed to tetrazine derivatives. Dehydrogenases remained active even at DHTz concentrations of 80 mg · L^?1, which completely inhibited bacterial growth. The compounds studied variously influence the kinetics of growth in the bacterial consortium; at the same time, they undergo biodegradation in soil by autochthonous microflora.     

An intervention to reduce work-related burnout in teachers.

The objective of the study was to develop and evaluate a 2-day burnout intervention program focused at enhancing coping with stresses observed in teachers' work. Karasek's job stress model was used as the theoretical framework. The aim of the intervention was to teach participants to deal better with high job demands and low job control. Some cognitive-behavioural methods of overcoming workload and enhancing a sense of self-mastery and relations with students were introduced in the workshop. 59 teachers were randomly assigned to an experimental or to a control group. Results showed that emotional exhaustion, perceived workload and somatic complaints decreased significantly in the intervention group. The greatest effect of the intervention was observed with regard to increased behavioural job control. It was concluded that teaching participants how to manage their work environment better could help them in changing their perception of stressful job characteristics, reducing emotional exhaustion and somatic complaints.     

Work conditions in agriculture as risk factors of spinal pain in postmenopausal women

The aim of the study was to evaluate the risk factors for spinal pain in Polish postmenopausal women working in agriculture. The study included 1751 randomly selected postmenopausal women aged 45–65?years. The women were exposed to hazardous work conditions, in particular the use of force and heavy lifting, often more than 10?kg and with frequency of at least once a day. Two-thirds of them suffered from spinal pain, mostly in the lumbar spine and less frequently in the cervical and thoracic spine. The prevalence of spinal pain depended on exposure to health risks associated with overwork, early onset of menopause and increasing age. The prevalence of pain in the lumbar spine correlated positively with higher frequency of heavy lifting and using excessive force during agricultural work. The severity of spinal pain correlates positively with the age of pain onset and negatively with level of education.